Boosting H2O2 generation by shortening the charge migration distance in BiPO4 nanocrystals

Abstract

The photocatalytic production of H2O2 has gained recognition as an economical and eco-friendly technology, but it suffers from limitations such as low production rates and difficulty in achieving high concentrations. This study was designed to overcome these limitations by preparing BiPO4 nanocrystals (BIP NCs) via high-temperature hydrolysis, and X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated that BIP NCs with particle sizes of 8.5 ± 3 nm were synthesized. In a photocatalytic performance test, only H2O and O2 were used to produce H2O2, resulting in an accumulation of H2O2 of up to 30.44 mM·g−1, as measured with the potassium titanium oxalate method; this value was 3.13 times greater than that of bulk BiPO4 (BIP-B). The resulting nanocrystals demonstrated superior electron-hole transport and separation efficiency compared to those of BIP-B, and H2O2 was formed in a one-step two-electron process. Furthermore, a film composed of a gas diffusion layer (GDL) and BIP NCs provided continuous accumulation of H2O2; a concentration of 7.23 mM was achieved after 96 h of reaction, and the stability of the film was confirmed by comparing scanning electron microscopy (SEM) images obtained before and after the reaction. Construction of a nanocrystalline structure to enhance the activities of photocatalysts and films and achieve continuous accumulation of H2O2 will provide insights into the photocatalytic production of highly concentrated H2O2.