Abstract
Based on the available crystal data, a linear correlation betweenR 0, the bond valence parameter for a Mo-containing chemical bond, and the Mo oxidation staten was developed for the first time. Using the “universal” value of the parameterB = 0.037 nm, the linear equations ofR 0-n for Mo-X (X: O, S, N, Cl and F) bonds were established. The oxidation-state independent Mo-O bond valence parameters,R 0 = 0.18788 nm andB = 0.03046 nm, published recently have been shown to be a special case of the linearly correlated functions. Some bond valence sum calculations in compounds containing only Mo-O bonds using these parameters are presented.
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