Abstract
New bond valence R0 parameters were derived for alkali– and alkaline-earth–oxygen pairs encountered in metal−organic compounds. A total of 7693 metal−oxygen bond lengths were extracted from structures deposited in the Cambridge Structural Database (CSD) and containing at least one carboxylate ligand bound to the metal. One hundred structures were individually analyzed for each metal. R0 values were computed using two different approaches: geometric mean and graphical fitting. In both cases, the bond valence parameter b was fixed at 0.37 Å. R0 values obtained using a geometric mean approach were 1.744 (Na–O), 2.094 (K–O), 2.228 (Rb–O), 2.412 (Cs–O), 1.661 (Mg–O), 1.933 (Ca–O), 2.090 (Sr–O), and 2.265 Å (Ba–O). These parameters yielded more accurate metal bond valence sums (BVS) and lower root-mean square deviations (RMSD) than those computed using R0 values currently available in the literature,1 which had been derived from the structures of inorganic oxides. The most significant improvement was observed for sodium (this work mean BVS = 1.01 v.u., RMSD = 0.116 v.u.; literature mean BVS = 1.18 v.u., RMSD = 0.226 v.u.; v.u.: valence units) and magnesium (this work mean BVS = 2.00 v.u., RMSD = 0.038 v.u.; literature mean BVS = 2.18 v.u., RMSD = 0.100 v.u.). More accurate bond valence sums and lower variances were also observed when the new set of R0 values was applied to metal–organic compounds featuring oxygenated ligands such as ethers, ketones, aldehydes, alcohols, and esthers. These parameters should be applicable to the structural and crystal-chemical analysis of metal−organic compounds ranging from coordination complexes to organic−inorganic extended hybrids.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.