Abstract

Si nanocrystals (Si-ncs) were prepared from n-type Si (100) wafers by using high-current pulsed electron beam irradiation in vacuum. High density (9.7 × 1014 cm−2) ultrafine Si-ncs (∼3 nm) embedded in amorphous Si layers (∼60 nm) exhibit blue photoluminescence emission at room temperature which can be attributed to the quantum confinement size effect. The pulse number is a key parameter which influences the photoluminescence intensity. Possible formation mechanisms of Si-ncs are discussed.

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