Abstract
AbstractBlock copolymer synthesis via a combination of ATRP and RAFT using click chemistry is reported for the first time. A RAFT agent with a terminal propargyl group (PTTC) was synthesized and was used to polymerize butyl acrylate and gave quantitative monomer conversion. Azide‐terminated p(tbA) was obtained by ATRP followed by reaction with sodium azide. Later, using CuBr‐PMDETA as catalyst via click chemistry, p(tBA)(ATRP) and p(BA)(RAFT) were reacted to get a block copolymer of p(tBA)(ATRP)‐b‐p(BA)(RAFT). Further, a total of 24 block copolymers were made by reacting four azido functional polymers with six propargyl functional polymers to obtain block copolymers via click chemistry. magnified image
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callSimilar Papers
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
