Blighia sapida Waste Biochar in Batch and Fixed-Bed Adsorption of Chloroquine Phosphate: Efficacy Validation Using Artificial Neural Networks.

Abstract

The present study investigated the potency of biochar prepared from Blighia sapida seedpods (BSSPs) in the uptake of chloroquine phosphate (CQP) from single-component batch and multicomponent fixed-bed adsorption systems. BSSPs presented a highly porous structure with a BET surface area of 1122.05 m2/g, to which adsorption efficiency correlated. The Dubinin-Radushkevich isotherm energy was obtained as 129.09 kJ/mol, confirming the chemisorption nature of the BSSP-CQP adsorption system. The efficiency of the artificial neural network (ANN) was evaluated using the lowest mean square error (MSE = 7.27) and highest correlation coefficient (R2 = 0.9910). A good agreement between the experimental results and the ANN-predicted data indicated the efficiency of the model. The percentage removal of 95.78% obtained for the column adsorption studies indicated the effectiveness of BSSPs in a multicomponent system. The mechanism of the interaction proceeded via hydrogen bonding and electrostatic attraction. This was confirmed by the high desorption efficiency (69.11%) with a HCl eluent. The degree of reversibility was found to be 2.95, indicating the reusability potential of BSSPs. BSSPs are therefore considered multilayered adsorbents with potential applications in pharmaceutical wastewater treatment.