Abstract

Seed oil blending is a novel approach that may enhance the oil antioxidant capacity. The study evaluated the effect of blending sunflower oil (SO) with pomegranate seed oil (BPSO) from blanched seeds (95 °C/ 3 min) on oxidative stability and antioxidant properties of the oil blends. SO and pomegranate seed oil from unblanched seeds (PSO) were used as controls. Blending SO with BPSO and PSO was assessed in the following respective proportions: 90:10, 85:15, and 80:20 (w/w) with respect to total phenolic content, total carotenoids content, tocopherols content, and fatty acid composition to establish the best blending ratio. An accelerated storage test was conducted using the best blending ratio (85:15) at 60 ± 2 °C for 20 days. The evolution of peroxide value, ρ-anisidine value and, total oxidation value, together with the depletion of the oils’ 2.2-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) and 2.2-diphenyl-1-picryl hydrazyl (DPPH) and radicals scavenging capacity were evaluated. Volatile oxidation compounds (VOCs) were assessed at the end of the accelerated storage test. Blended oils exhibited better oxidative stability than SO. Nevertheless, the oxidative stability of SO:PSO and SO:BPSO blends did not significantly vary. Additionally, blended oils showed a lower rate of DPPH and ABTS radical scavenging capacity depletion than SO, although this did not significantly vary between the oil blends. The concentration of VOCs was significantly higher in SO than blended oils. No significant difference in the content of VOCs was observed between SO:PSO and SO:BPSO blends. The findings of this study are valuable to the food industry, which is presently interested in nonconventional oils and functional foods to improve health and human nutrition.

Highlights

  • Lipid oxidation is one of the major causes of product quality deterioration in the food industry, those high in polyunsaturated fatty acids (PUFA) such as edible seed oil due to their high sensitivity to oxidation [1]

  • The fatty acid content of sunflower oil (SO) significantly varied from the blended oils, no significant differences in the fatty acid composition were observed among the blended oils

  • pomegranate seed oil from unblanched seeds (PSO) and BPSO were characterised by high levels of PUFA, which ranged between 75.18 and 78.59%, and this may be attributed to punicic acid, an 18:3 cis-9, trans-11, cis-13 fatty acid unique to pomegranate seed oil

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Summary

Introduction

Lipid oxidation is one of the major causes of product quality deterioration in the food industry, those high in polyunsaturated fatty acids (PUFA) such as edible seed oil due to their high sensitivity to oxidation [1]. Lipid oxidation has detrimental effects both on food quality and human health Synthetic antioxidants such as butylated hydroxyanisole, butylated hydroxyl toluene, and propylgallate have been primarily used to control lipid oxidation in edible seed oil. The blending of two or more seed oil with different chemical properties has gained popularity due to its ability in altering the fatty acid profiles, improve natural antioxidants, oxidative properties, nutritional qualities, and industrial applications of the oils at relatively low cost [4]. Conventional seed oil significantly loses its functional and nutritional properties and oxidative stability

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