Black TiO2-infused polydimethylsiloxane composites for efficient solar-assisted water evaporation and thermoelectric energy generation

Abstract

Solar assisted interfacial water evaporation through the strategic localization of solar- thermal energy conversion by relying on the air–water interface has garnered significant interest owing to its enhanced efficiency in a variety of applications, from water purification to energy generation. Nevertheless, achieving utterly improved thermal management to enhance the efficiency of solar heat consumption is still quite complex. Herein, we created special composites of black titanium dioxide and polydimethylsiloxane (B-TiO2/PDMS) aiming effectively harvest a broad range of spectrum of solar radiation for the benefit of improving energy production and aid for water purification. The B-TiO2/PDMS sponge possesses an impressive optical to thermal transformation as an outcome, keeping a constant surface temperature of 66 °C, as opposed to 41.6 °C for PDMS sponge at typical 1 sun intensity for 10 min. This solar evaporation system constitutes a greater evaporation rate of 1.39 Kg m−2h−1 with a photothermal conversion efficiency of 70.8 % under 1 sun illumination. To accomplish integrated thermoelectric power generation during solar evaporation, the thermoelectric (TE) module is used as an insulating medium, succeeding an optimal yield of 30 mV under 1 sun. Furthermore, the as prepared B-TiO2/PDMS sponge achieved notable mechanical resilience and incredible adaptability, offering a viable approach for thermal management and cooperative way to utilize solar powered evaporation to produce potable water and energy.