Abstract

This work reports the syntheses of tBuLH and tBuLMeH, and their complexes [Ir(dfppy)2(tBuL)]·2CH3OH (1) and Ir(dfppy)2(tBuLMe)] (2), and the influence of substituent groups –C(CH3)3 and –CH3 on their photochromic and luminescence behaviors.

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