Abstract
AbstractThe reaction of bis(sulfonyl)iodonium ylides α−γ with triphenylethylene (2a) and tetraphenylethylene (2b) affords insertion products into the alkenyl and phenyl carbon−hydrogen bonds of the substrate. A mechanistically perplexing feature is the diversity displayed in the reactivity pattern of the bis(sulfonyl)iodonium ylides in their reaction with the phenylated alkenes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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