Bisphenol A removal in treated wastewater matrix at neutral pH using magnetic graphite intercalation compounds as persulfate activators.

Abstract

Effluents of municipal wastewater treatment plants (WWTPs) are major sources for releasing contaminants of emerging concern (CECs) into the aquatic environment, which can result in negative effects on aquatic ecosystems and, as a consequence, on humans. Herein, the graphite intercalation concept was used to synthesize heterogeneous catalysts to degrade bisphenol A (BPA) as a model CEC in municipal WWTP effluents at neutral pH. The catalyst was synthesized using the simple molten salt method and showed several benefits, such as iron leaching prevention and stability in environmental matrices. Different methods were applied to describe the catalyst's structural characteristics. The proposed system removed 99.3% of BPA in 75 min using 2 g/L of the synthesized catalyst and 1.19 g/L (5 mM) persulfate at neutral pH. Quenching experiments showed that catalytic activities and BPA removals were significantly aided by both radical and non-radical pathways through the generation of free radicals and singlet oxygen (1 O2 ). Furthermore, the reuse of recycled synthesized catalyst was investigated on treated urban wastewater, and the results showed that the catalyst could degrade BPA from the wastewater in consecutive cycles, demonstrating its applicability under real conditions. PRACTITIONER POINTS: BPA was effectively removed from the effluents of municipal WWTPs at neutral pH. A new catalyst (magnetic GIC) was fabricated for heterogeneous catalytic systems. The catalyst activates persulfate to generate free radicals and 1 O2 , indicating that radical and non-radical pathways contribute to BPA degradation. The catalyst showed the ability to remove BPA even in the sixth cycle of use, demonstrating its stability and reusability.