Abstract
ESR detection of bis(perfluoroalkyl) nitroxides 11 and perfluoroalkyl nitroalkyl nitroxides 12 in accord with expected products suggests an electron transfer mechanism for the reactions between nitroalkane salts 1 and perfluorodiacyl peroxides 2. Nitroxides 11 and 12 are the spin-adducts of radical intermediates R 1R 2C ·NO 2 ( 3) and R · f ( 10) with the nitroso-trap R fNO ( 9) generated in the reactions. These reactions have served as a useful technique in mechanistic studies of one-electron oxidations of some nitrogen-containing substrates.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Paper version not known
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
