Abstract

Abstract The preparations of some bisoxalatobisfluoroaluminates having the general formula M 3 [Al(C 2 O 4 ) 2 F 2 .3H 2 O], where M=K + , Na + and [Co(NH 3 ) 6 ] 3+ , and a bisoxalatobisfluorogallate, [Co(NH 3 ) 6 ] [Ga(C 2 O 4 ) 2 F 2 ].3H 2 O, are described. The compounds are characterised by chemical analyses, TGA, IR spectroscopy and X-ray powder photography. IR spectra support the presence of chelating oxalate ligands in these compounds. On isothermal heating at 100–130°C the compounds yield their respective anhydrous products.

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