Abstract
The title compound, (C12H16N2)2[PbI6], is an organic–inorganic salt, with two doubly protonated N-(1-naphthyl)ethylenediamine groups as the cations and one octahedral hexaiodoplumbate(II) as the anion. The stucture consists of alternating inorganic and organic layers parallel to the bc plane. Simple face-to-face aromatic stacking interactions occur between parallel naphthalene systems in the organic layers, and N—H⋯I hydrogen bonds between the ethylenediammonium groups and PbI64− octahedra stabilize the structure. The slightly distorted PbI6 octahedra are isolated from each other, with the Pb atom located on a centre of inversion.
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