BisGMA/EPDM/amine functionalised MWCNTs based nanocomposites

Abstract

Purpose– This paper aims to focus on the development and study properties of bisphenol-A glycidyldimethacrylate (BisGMA) and ethylene–propylene–diene monomer (EPDM) blend-based nanocomposites containing amine-functionalised multi-walled carbon nanotubes (MWCNT-NH2) as a compatibiliser.Design/methodology/approach– First, BisGMA was synthesised from epoxy and methacrylic acid followed by the amine functionalisation of MWCNTs. A novel two-roll milling technique was then conducted to prepare nanocomposite specimens with MWCNT-NH2 as compatibiliser. Effect of MWCNT-NH2 content on the mechanical, thermal, electrical, corrosive and water absorption properties of the nanocomposites was investigated and results have been reported.Findings– The results of the present work reveal that MWCNT-NH2 acts as a potential compatibiliser and nanofiller in BisGMA/EPDM blend-based nanocomposites. The authors report here that the nanocomposites exhibit improved mechanical, thermal and electrical properties with increased addition of MWCNT-NH2. Moreover, desirable results are obtained at 5 phr of nanofiller loading beyond which the properties deteriorate due to particle agglomeration. The nanocomposites display negligible corrosion and water absorption characteristics. Thus, the above fabricated nanocomposites with optimum compatibiliser content can serve as low-cost structural, thermal and electrical materials which can also be utilised in corrosive and moist environments.Research limitations/implications– The present investigation has come up with the successful and cost-effective fabrication of BisGMA/EPDM blend-based nanocomposites with optimum nanofiller/compatibiliser (MWCNT-NH2) content that can be used for a wide range of structural, thermal and electrical projects, as it is corrosion and moisture resistant. It is also the most durable from the mechanical point of view.Originality/value– The above nanocomposites have never been designed before.