Year-end Sale % OFF 
Abstract
In the title triangulo-triruthenium compound, [Ru3(C25H22As2)(C18H15Sb)(CO)9], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and arsine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted phenyl rings make dihedral angles of 84.3 (3), 80.4 (3) and 70.5 (3)° with each other. The dihedral angles between the two phenyl rings are 85.9 (3) and 75.2 (3)° for the two diphenylarsine groups. In the crystal packing, molecules are linked into chains down the c axis via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure.
Highlights
[Ru3(C25H22As2)(C18H15Sb)(CO)9], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and arsine ligands are equatorial with respect to the
The dihedral angles between the two phenyl rings are 85.9 (3) and 75.2 (3)
Molecules are linked into chains down the c axis via intermolecular C—H O hydrogen bonds
Summary
11800 USM, Penang, Malaysia, and bX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia. [Ru3(C25H22As2)(C18H15Sb)(CO)9], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and arsine ligands are equatorial with respect to the. Each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted phenyl rings make dihedral angles of. The dihedral angles between the two phenyl rings are 85.9 (3) and 75.2 (3). Molecules are linked into chains down the c axis via intermolecular C—H O hydrogen bonds. Weak intermolecular C—H interactions further stabilize the crystal structure
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
