Abstract
In the title compound, [Sn4(CH3)8(C8H9O2)2Cl2O2], the tetranuclear complex molecule has crystallographically imposed inversion symmetry. The coordination polyhedron about the two central Sn atoms is distorted trigonal–bipyramidal, whilst the two peripheral metal atoms bonded to the carboxylate groups have a distorted octahedral coordination geometry. In the crystal, molecules are connected by long Sn⋯O contacts [3.139 (11) Å], forming chains along [011].
Highlights
In the title compound, [Sn4(CH3)8(C8H9O2)2Cl2O2], the tetranuclear complex molecule has crystallographically imposed inversion symmetry
Bipyramidal, whilst the two peripheral metal atoms bonded to the carboxylate groups have a distorted octahedral coordination geometry
Complex molecules are connected by long Sn···O interaction
Summary
In the title compound, [Sn4(CH3)8(C8H9O2)2Cl2O2], the tetranuclear complex molecule has crystallographically imposed inversion symmetry. 0.13 0.11 0.05 mm Siemens SMART CCD areadetector diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1996) H-atom parameters constrained max = 0.86 e Å3 Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.030 Å; R factor = 0.047; wR factor = 0.130; data-to-parameter ratio = 17.9.
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