Abstract

Two new bis(bibenzyl) ethers, perrottetin E-11′-methyl ether and 14-hydroxyperrottetin E-11′-methyl ether were isolated from an ethyl acetate extract of the liverwort Pellia endiviifolia together with the previously known bis(bibenzyl) ether, perrottetin E and their structures characterized by spectroscopic methods, chemical evidence and total synthesis. The present results strongly support Schuster's phylogenic classification of the Metzgeriales and Jungermanniales.

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