Abstract
The title compound, (C8H12N)2[MoS4], was synthesized by the aqueous reaction of ammonium tetrathiomolybdate with benzyl(methyl)amine in a 1:2 molar ratio. The structure consists of a slightly distorted tetrahedral [MoS4]2− dianion and two crystallographically independent benzyl(methyl)ammonium cations, with all atoms located in general positions. The cations and anions are linked by weak N—H...S and C—H...S interactions, the strength and number of which can explain the observed Mo—S bond distances.
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