Abstract
The asymmetric unit of the binuclear centrosymmetric title compound, [Er2(C12H14O4)2(C12H15O4)2(C12H8N2)2(H2O)2]·2H2O, contains one ErIII atom, one coordinated water molecule, one 1,10-phenanthroline (phen) ligand, two differently coordinated adamantane-1,3-dicarboxylate (H2L) ligands and one lattice water molecule. The ErIII ion is eight-coordinated by four O atoms from bridging L 2−, one O atom from HL −, one O atom from the coordinated water and two N atoms from a phen ligand. Extensive O—H⋯O hydrogen-bonding interactions result in the formation of chains which are further linked into a layer-like network by π–π stacking interactions centroid–centroid distance = 3.611 (3) Å] between adjacent phen ligands belonging to neighbouring chains. The carboxy group of the HL − ligand is equally disordered over two positions.
Highlights
Crystal dataKey indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.006 Å; disorder in main residue; R factor = 0.030; wR factor = 0.067; data-to-parameter ratio = 17.1
The asymmetric unit of the binuclear centrosymmetric title compound, [Er2(C12H14O4)2(C12H15O4)2(C12H8N2)2(H2O)2]2H2O, contains one ErIII atom, one coordinated water molecule, one 1,10-phenanthroline ligand, two differently coordinated adamantane-1,3-dicarboxylate (H2L)
The ErIII ion is eight-coordinated by four O atoms from bridging L2, one O
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.006 Å; disorder in main residue; R factor = 0.030; wR factor = 0.067; data-to-parameter ratio = 17.1
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More From: Acta Crystallographica Section E Structure Reports Online
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