Abstract
In the title dinuclear CdII complex, [Cd2(C2N4O2)2(C10H8N2)2(H2O)2], each Cd atom is in a slightly distorted octahedral coordination by two N atoms and one O atom of two 1H-tetrazole-5-carboxylate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom. The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent CdII atoms. The complex reveals molecular C i symmetry. Extensive O—H⋯O hydrogen bonding plays an important role in the crystal packing.
Highlights
In the title dinuclear CdII complex, [Cd2(C2N4O2)2(C10H8N2)2(H2O)2], each Cd atom is in a slightly distorted octahedral coordination by two N atoms and one O atom of two 1H-tetrazole-5-carboxylate (TZC) ligands, two N atoms of a 2,20 -bipyridyl ligand and one water O atom
The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent CdII atoms
Extensive O—H O hydrogen bonding plays an important role in the crystal packing
Summary
R factor = 0.025; wR factor = 0.066; data-to-parameter ratio = 10.5. In the title dinuclear CdII complex, [Cd2(C2N4O2)2(C10H8N2)2(H2O)2], each Cd atom is in a slightly distorted octahedral coordination by two N atoms and one O atom of two 1H-tetrazole-5-carboxylate (TZC) ligands, two N atoms of a 2,20 -bipyridyl ligand and one water O atom. The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent CdII atoms. Extensive O—H O hydrogen bonding plays an important role in the crystal packing
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