Abstract
In the title complex, [Sn(C7H6F)2(C8H5N2S3)2], including the weak Sn—N interactions, the SnIV atom is situated in a distorted trans-octahedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanylidene-4,5-dihydro-1,3,4-thiodiazole-2-thiolate ligands. The apical positions are occupied by two C atoms of 4-fluorobenzyl groups.
Highlights
In the title complex, [Sn(C7H6F)2(C8H5N2S3)2], including the weak Sn—N interactions, the SnIV atom is situated in a distorted trans-octahedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanylidene-4,5dihydro-1,3,4-thiodiazole-2-thiolate ligands
The apical positions are occupied by two C atoms of 4-fluorobenzyl groups
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)
Summary
R factor = 0.060; wR factor = 0.102; data-to-parameter ratio = 14.7. In the title complex, [Sn(C7H6F)2(C8H5N2S3)2], including the weak Sn—N interactions, the SnIV atom is situated in a distorted trans-octahedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanylidene-4,5dihydro-1,3,4-thiodiazole-2-thiolate ligands. The apical positions are occupied by two C atoms of 4-fluorobenzyl groups
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