Abstract
In the crystal structure of the title compound, [Ni(NCS)2(C7H7NO)2(CH3OH)2], the Ni2+ cations are coordinated by two thiocyanate anions, two 3-acetylpyridine ligands and two methanol molecules within slightly distorted NiN4O2 octahedra. The asymmetric unit consists of one Ni2+ cation, which is located on a center of inversion, as well as one thiocyanate anion, one 3-acetylpyridine ligand and one methanol molecule in general positions. The discrete complexes are linked by two pairs of O—H⋯O hydrogen bonds between the hydroxy H atom and the acetyl O atom into chains along the b axis.
Highlights
In the crystal structure of the title compound, [Ni(NCS)2(C7H7NO)2(CH3OH)2], the Ni2+ cations are coordinated by two thiocyanate anions, two 3-acetylpyridine ligands and two methanol molecules within slightly distorted NiN4O2 octahedra
The asymmetric unit consists of one Ni2+ cation, which is located on a center of inversion, as well as one thiocyanate anion, one 3-acetylpyridine ligand and one methanol molecule in general positions
R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger
Summary
Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-EythStrasse 2, 24118 Kiel, Germany. The discrete complexes are linked by two pairs of O—H O hydrogen bonds between the hydroxy H atom and the acetyl O atom into chains along the b axis
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