Abstract

In the title compound, [Ni(C8H7O4)2{(CH3)2SO}2], the NiII atom is located on a crystallographic centre of symmetry and has a distorted octa­hedral coordination geometry of type MO6. The bidentate dehydro­acetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and the dimethyl sulfoxide (DMSO) ligands are weakly coordinated through their O atoms in the axial positions.

Highlights

  • In the title compound, [Ni(C8H7O4)2{(CH3)2SO}2], the Ni atom is located on a crystallographic centre of symmetry and has a distorted octahedral coordination geometry of type

  • The bidentate dehydroacetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and the dimethyl sulfoxide (DMSO) ligands are weakly coordinated through their O atoms in the axial positions

  • Symmetry codes: (ii) x+1, −y+3/2, z+1/2; (iii) x, y+1, z

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Summary

Structure Reports

Bendaas,a Magali Allainc and Gilles Bouetd a Laboratoire d’Electrochimie des Matériaux, Moléculaires et Complexes, Département de Génie des Procédés, Faculté des Science de l’Ingénieur, Université.

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