Abstract
In the centrosymmetric dinuclear title compound, [Pb2(C10H6NO2)2(CH3COO)2(C2H5OH)2], one O atom of the carboxylate group of the quinoline-2-carboxylate anion connects the two PbII atoms. The PbII atom is surrounded by four O atoms and one N atom in a Ψ-octahedral PbO4NE geometry (E is the electron lone pair). Two longer Pb⋯O interactions distort the geometry towards a Ψ-square-antiprism. Intermolecular O—H⋯O hydrogen bonds link the molecules.
Highlights
In the centrosymmetric dinuclear title compound, [Pb2(C10H6NO2)2(CH3COO)2(C2H5OH)2], one O atom of the carboxylate group of the quinoline-2-carboxylate anion connects the two PbII atoms
The PbII atom is surrounded by four O atoms and one N atom in a É-octahedral PbO4NE geometry (E is the electron lone pair)
Two longer PbÁ Á ÁO interactions distort the geometry towards a É-square-antiprism
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.007 A; R factor = 0.029; wR factor = 0.073; data-to-parameter ratio = 17.3. In the centrosymmetric dinuclear title compound, [Pb2(C10H6NO2)2(CH3COO)2(C2H5OH)2], one O atom of the carboxylate group of the quinoline-2-carboxylate anion connects the two PbII atoms. The PbII atom is surrounded by four O atoms and one N atom in a É-octahedral PbO4NE geometry (E is the electron lone pair). Two longer PbÁ Á ÁO interactions distort the geometry towards a É-square-antiprism. Intermolecular O—HÁ Á ÁO hydrogen bonds link the molecules.
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