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Abstract
In the title compound, [Cd(NO3)2(C4H5N3)2(H2O)2]·H2O, the Cd atom is seven-coordinated by two 2-aminopyrimidine molecules, two water molecules, one bidentate nitrate anion and one monodentate nitrate anion. A network of N—H⋯O, N—H⋯N and O—H⋯O hydrogen bonds helps to consolidate the crystal structure.
Highlights
In the title compound, [Cd(NO3)2(C4H5N3)2(H2O)2]ÁH2O, the Cd atom is seven-coordinated by two 2-aminopyrimidine molecules, two water molecules, one bidentate nitrate anion and one monodentate nitrate anion
Symmetry codes: (i) −x, −y, −z; (ii) −x+1, −y, −z+1; (iii) −x+1, y+1/2, −z+1/2; (iv) −x, −y+1, −z+1; (v) x, −y+1/2, z−1/2; (vi) x, y+1, z; (vii) x, −y+3/2, z+1/2
Summary
Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.005 A; R factor = 0.030; wR factor = 0.079; data-to-parameter ratio = 16.0. In the title compound, [Cd(NO3)2(C4H5N3)2(H2O)2]ÁH2O, the Cd atom is seven-coordinated by two 2-aminopyrimidine molecules, two water molecules, one bidentate nitrate anion and one monodentate nitrate anion. A network of N—HÁ Á ÁO, N—HÁ Á ÁN and O—HÁ Á ÁO hydrogen bonds helps to consolidate the crystal structure. Related literature For related literature, see: Cui et al (2003)
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