Abstract
In the title complex molecule, [CdBr2(C10H8N2)2], the CdII ion is six-coordinated by two cis-arranged bromide anions and four N atoms of two bidentate 2,2′-bipyridine ligands in a distorted octahedral geometry. The dihedral angle formed by the mean planes through the bipyridine ligands is 87.01 (11)°. In the crystal packing, π–π stacking interactions [centroid–centroid distances = 3.837 (6) and 3.867 (11) Å] link adjacent complex molecules into chains running parallel to the b axis. The chains are further connected by intermolecular C—H⋯Br hydrogen bonds into a three-dimensional network.
Highlights
College of Materials Science and Chemical Engineering, Jinhua College of Profession and Technology, Jinhua, Zhejiang 321017, People’s Republic of China
In the title complex molecule, [CdBr2(C10H8N2)2], the Cd ion is six-coordinated by two cis-arranged bromide anions and four N atoms of two bidentate 2,20 -bipyridine ligands in a distorted octahedral geometry
The dihedral angle formed by the mean planes through the bipyridine ligands is 87.01 (11)
Summary
R factor = 0.038; wR factor = 0.136; data-to-parameter ratio = 19.0. In the title complex molecule, [CdBr2(C10H8N2)2], the Cd ion is six-coordinated by two cis-arranged bromide anions and four N atoms of two bidentate 2,20 -bipyridine ligands in a distorted octahedral geometry. The dihedral angle formed by the mean planes through the bipyridine ligands is 87.01 (11). Centroid distances = 3.837 (6) and 3.867 (11) Å] link adjacent complex molecules into chains running parallel to the b axis. H Br hydrogen bonds into a three-dimensional network
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