Abstract
In the title compound, [Mn(C12H9O2)2(C7H6N2)2]·H2O, the MnII ion is located on a twofold rotation axis and six-coordinated, displaying a distorted MnN2O4 octahedral geometry. The crystal packing is stabilized by N—H⋯O hydrogen bonds, which give rise to a one-dimensional structure along [001], and π–π interactions between the imidazole rings and between the benzene rings of the 2-(naphthalen-1-yl)acetate ligands [centroid–centroid distances = 3.761 (3) and 3.728 (4) Å]. The contribution of the electron density associated with the disordered water molecules was not considerd in the final structure model.
Highlights
MnII ion is located on a twofold rotation axis and sixcoordinated, displaying a distorted MnN2O4 octahedral geometry
The contribution of the electron density associated with the disordered water molecules was not considerd in the final structure model
In the title mononuclear complex (Fig. 1), the MnII ion is located on a twofold rotation axis and six-coordinated by two
Summary
Bis(1H-benzimidazole-jN3)bis[2(naphthalen-1-yl)acetato-j2O,O0 ]manganese(II) monohydrate Wanga a College of Environment Science and Spatial Infomatics, China University of Mining & Technology, Xuzhou, Jiangsu 221008, People’s Republic of China, bDepartment of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, People’s Republic of China, and cJiangsu Marine Resources Development Research Institute, Huaihai Institute of Technology, Lianyungang 222005, People’s Republic of
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