Abstract
The CaII ion of the title complex, [Cu(SCN)(C8H20N4)]2[Ca(NCS)4(H2O)2].2H2O, is situated at an inversion center. The coordination geometry around the CuII ion is a symmetrical square pyramid with the tetraamine N atoms equatorial and thiocyanato S atom axial. The four donor N atoms of the macrocyclic ligand form a buckled plane, the CuII ion lies 0.553 (1) Å out of this plane towards the thiocyanato group. The hydrogen bonds between water molecules and thiocyanato groups help stabilize the crystal structure. A water molecule binds the CuII complex and the CaII complex together through hydrogen bonds.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section C Crystal Structure Communications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
