Abstract
In the title compound, [Zn(SO4)(C12H8N2)2]·C3H8O2, the ZnII ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The ZnII ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol molecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N2C2 groups is 83.26 (13)°. In the crystal, the complex molecule and the propane-1,2-diol molecule are connected through a pair of O—H⋯O hydrogen bonds.
Highlights
In the title compound, [Zn(SO4)(C12H8N2)2]ÁC3H8O2, the ZnII ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10phenanthroline ligands and one O atom from a monodentate sulfate ligand
The ZnII ion lies on a twofold rotation axis
The sulfate ligand and propane-1,2-diol molecules are disordered across the twofold rotation axis
Summary
In the title compound, [Zn(SO4)(C12H8N2)2]ÁC3H8O2, the ZnII ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10phenanthroline ligands and one O atom from a monodentate sulfate ligand. The ZnII ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol molecules are disordered across the twofold rotation axis. The complex molecule and the propane-1,2-diol molecule are connected through a pair of O—HÁ Á ÁO hydrogen bonds. Related literature For the ethane-1,2-diol solvate of the title complex, see: Zhu et al (2006) and for the propane-1,3-diol solvate of the title complex, see: Cui et al (2010). Crystal data [Zn(SO4)(C12H8N2)2]ÁC3H8O2 Mr = 597.93 Monoclinic, C2=c a = 17.3913 (10) Ab = 12.9247 (7) Ac = 13.2214 (7) A = 123.248 (5)
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