Bis[tris-(diiso-butyl-dithio-carbamato)-μ3-sulfido-tri-μ2-di-sulfido-trimolybdenum(IV)] sulfide tetra-hydro-furan monosolvate.

Abstract

The title compound, [Mo3(C9H18NS2)3(S2)3S]2S, crystallizes on a general position in the monoclinic space group P21/n (No. 14). The cationic [Mo3S7(S2CNiBu2)3]+ fragments are joined by a mono-sulfide dianion that forms close S⋯S contacts to each of the di-sulfide ligands on the side of the Mo3 plane opposite the μ3 2- ligand. The two Mo3 planes are inclined at an angle of 40.637 (15)°, which gives the assembly an open clamshell-like appearance. One μ6-S2-⋯S2 2- contact, at 2.4849 (14) Å, is appreciably shorter than the remaining five, which are in the range 2.7252 (13)-2.8077 (14) Å.