Abstract

The title compound, (C24H20P)2[Mo(C7H4O4)2O2], contains a distorted octahedral molybdenum(VI) complex having the characteristic cis-MoO2 2+ group and the ligand 2,3-dihydroxybenzoic acid coordinated through the two phenolate O atoms, while the carboxyl group is not deprotonated. No π–π overlap between the benzene rings of the ligands or those of the tetraphenylphosphonium ions is observed.

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