Year-end Sale % OFF 
Abstract
In the title compound, (C24H20As)2[Co2(C6H6NO6)2(OH)2]·8H2O, the CoIII atom in the binuclear centrosymmetric anion is octahedrally surrounded by one N atom and three O atoms of the tetradentate nitrilotriacetate ligand and two μ-hydroxide ligands. The crystal packing is controlled by C—H⋯O and O—H⋯O hydrogen-bonding interactions. The crystal employed in this study proved to be a two-component twin around (01).
Highlights
H atoms treated by a mixture of independent and constrained refinement max = 0.41 e Å3
In the title compound, (C24H20As)2[Co2(C6H6NO6)2(OH)2]8H2O, the CoIII atom in the binuclear centrosymmetric anion is octahedrally surrounded by one N atom and three O atoms of the tetradentate nitrilotriacetate ligand and two hydroxide ligands
The crystal packing is controlled by C—
Summary
H atoms treated by a mixture of independent and constrained refinement max = 0.41 e Å3. Min = 0.36 e Å3 a Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein. 9300, South Africa, and bDepartment of Chemistry, University of Cambridge, Lensfield Rd, Cambridge CB2 1EW, England. Symmetry code: (i) x þ 1; y þ 2; z þ 1. R factor = 0.030; wR factor = 0.098; data-to-parameter ratio = 54.0. In the title compound, (C24H20As)2[Co2(C6H6NO6)2(OH)2]8H2O, the CoIII atom in the binuclear centrosymmetric anion is octahedrally surrounded by one N atom and three O atoms of the tetradentate nitrilotriacetate ligand and two hydroxide ligands. The crystal packing is controlled by C—. H O and O—H O hydrogen-bonding interactions. The crystal employed in this study proved to be a two-component twin around (011)
Sign-in/Register to view highlights & summary 
Published Version (
Free)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
