Abstract
In the title compound, [Zn(C20H16N3S2)2]·CH3CN, two different Schiff base moieties coordinate to the central ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octahedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C—H⋯N hydrogen-bonding interactions.
Highlights
The crystal packing is consolidated by weak C—H N hydrogen-bonding interactions
The crystal packing is consolidated by weak C—H···N hydrogen bonding interactions (Table 2)
The crystal was placed in the cold stream of an Oxford Cryosystems open-flow nitrogen cryostat (Cosier & Glazer, 1986) with a nominal stability of 0.1 K
Summary
Ravoof,* Siti Aminah Omar, Mohamed Ibrahim Mohamed Tahir and Karen A. R factor = 0.038; wR factor = 0.081; data-to-parameter ratio = 17.8
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