Bis[(S)-2-(4-tert-butyl-4,5-dihydrooxazol-2-yl)phenyl]phenylphoshine-kappa(2)N,P](1,3-dimethyl-pi-allyl-kappa(3)C)palladium(II) hexafluorophosphate and (S)(P)-[bis[(S)-2-(4-tert-butyl-4,5-dihydrooxazol-2-yl)phenyl]phenylphosphine-kappa(2)N,P]dichloropalladium(II).

Dai Masui,Takamichi Yamagishi,Motowo Yamaguchi,Masatoshi Ohnuki

doi:10.1107/s010827010302170x

Bis[(S)-2-(4-tert-butyl-4,5-dihydrooxazol-2-yl)phenyl]phenylphoshine-kappa(2)N,P](1,3-dimethyl-pi-allyl-kappa(3)C)palladium(II) hexafluorophosphate and (S)(P)-[bis[(S)-2-(4-tert-butyl-4,5-dihydrooxazol-2-yl)phenyl]phenylphosphine-kappa(2)N,P]dichloropalladium(II).

Dai Masui, Takamichi Yamagishi + Show 2 more

https://doi.org/10.1107/s010827010302170x

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Journal: Acta crystallographica. Section C, Crystal structure communications	Publication Date: Oct 31, 2003
Citations: 3

Affiliation: Tokyo Metropolitan University

#Allyl Complex #Phosphine Ligand + Show 3 more

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Abstract

In the structures of the title compounds, [Pd(C(5)H(9))(C(32)H(37)N(2)O(2)P)]PF(6) and [PdCl(2)(C(32)H(37)N(2)O(2)P)], the bis(dihydrooxazolyl)phosphine ligand is N,P-bidentate, with S chirality on the P atom. In the allyl complex, the pi-allyl ligand ligates in a syn-syn-kappa(3)C manner.

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