Abstract
The asymmetric unit of the title iron hybrid fluoride, (C3H12N2)2[FeF6]F·3H2O, contains two propane-1,3-diaminium [(H2dap)2+] cations, an octahedral [FeF6]3− anion, an isolated F− anion and three water molecules of solvation. Each [FeF6]3− anion is surrounded by four separate hydrogen-bonded water molecules in the equatorial sites and by five separate aminium cation donor groups. The axial F atoms are only involved in N—H⋯F hydrogen bonds, resulting in a three-dimensional structure.
Highlights
(C3H12N2)2[FeF6]F3H2O, contains two propane-1,3-diaminium [(H2dap)2+] cations, an octahedral [FeF6]3 anion, an isolated F anion and three water molecules of solvation
H atoms treated by a mixture of independent and constrained refinement max = 0.42 e Å3
The axial F atoms are only involved in N—H F hydrogen bonds, resulting in a three-dimensional structure
Summary
H atoms treated by a mixture of independent and constrained refinement max = 0.42 e Å3. Unité de Recherche 99/UR12-30, Faculté des Sciences de Bizerte, 7021 Jarzouna, Tunisia, and bLaboratoire des Oxydes et Fluorures - UMR 6010 CNRS, Institut de Recherche en Ingénierie Moléculaire et Matériaux, Fonctionnels, IRIM2F FR CNRS. R factor = 0.031; wR factor = 0.093; data-to-parameter ratio = 13.3. (C3H12N2)2[FeF6]F3H2O, contains two propane-1,3-diaminium [(H2dap)2+] cations, an octahedral [FeF6]3 anion, an isolated F anion and three water molecules of solvation. Each [FeF6]3 anion is surrounded by four separate hydrogenbonded water molecules in the equatorial sites and by five separate aminium cation donor groups. The axial F atoms are only involved in N—H F hydrogen bonds, resulting in a three-dimensional structure
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
