Abstract
In the title compound, [Co(C5H7O2)2(C12H8N2)], the CoII cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetylacetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octahedral environment, with Co—O bond lengths of 2.0565 (11) and 2.0641 (11) Å and Co—N bond lengths of 2.1630 (12) Å. In the crystal, there are no significant hydrogen-bonding or π–π interactions.
Highlights
In the title compound, [Co(C5H7O2)2(C12H8N2)], the CoII cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetylacetonate ligands and two N atoms from a 1,10-phenanthroline ligand in a slightly distorted octahedral environment, with Co—O bond lengths of 2.0565 (11) and 2.0641 (11) Aand Co—N bond lengths of 2.1630 (12) A
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: PV2467)
Is not relevant to the choice of reflections for refinement
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.002 A; R factor = 0.032; wR factor = 0.089; data-to-parameter ratio = 17.1. Crystal data [Co(C5H7O2)2(C12H8N2)] Mr = 437.35 Orthorhombic, Pbna a = 10.2660 (2) Ab = 12.6981 (3) Ac = 15.5885 (3) A
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