Abstract
In the title complex, [Ni(C7H14N4OS)2]Cl2, the NiII ion is six-coordinated in a distorted octahedral geometry by four N atoms from the two imine and two oxime groups, and two S atoms from the thione groups. Two chloride ions complete the asymmetric unit. In the crystal, molecules are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds into an infinite chain propagating along [101].
Highlights
Structure ReportsBis{N-ethyl-2-[3-(hydroxyimino-jN)butan-2-ylidene]hydrazinecarbothioamide-j2N2,S}nickel(II) dichloride School of Chemical Sciences, Universiti Sains Malaysia, Minden, Penang, Malaysia, Faculty of Science, Sabha University, Libya, cDepartment of Chemistry, International University of Africa, Sudan, and dX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia
In the title complex, [Ni(C7H14N4OS)2]Cl2, the NiII ion is sixcoordinated in a distorted octahedral geometry by four N atoms from the two imine and two oxime groups, and two S atoms from the thione groups
In this paper we report the crystal structure of bis{Nethyl-2-[2-(hydroxyimino-κN)butan-2-ylidene]hydrazinecarbothioamide-κ2N2,S}nickle(II)dichloride
Summary
Bis{N-ethyl-2-[3-(hydroxyimino-jN)butan-2-ylidene]hydrazinecarbothioamide-j2N2,S}nickel(II) dichloride School of Chemical Sciences, Universiti Sains Malaysia, Minden, Penang, Malaysia, Faculty of Science, Sabha University, Libya, cDepartment of Chemistry, International University of Africa, Sudan, and dX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia
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