Abstract
In the title compound, [Ag(C14H10N4O)2]CF3SO3, two N atoms from two independent pyridyl rings of two N′-3-cyanobenzylideneisonicotinohydrazide ligands coordinate to the unique AgI ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked together by Ag⋯N interactions, with Ag⋯N separations of 2.877 (2) and 3.314 (2) Å. On the other hand, one CF3SO3 − anion interacts with hydrazone groups of two neighbouring ligands via N—H⋯O hydrogen bonds. These weak intermolecular interactions contribute to the formation of supramolecular chains. In addition, there are Ag⋯O interactions [2.787 (2) Å] between Ag and O atoms from adjacent chains.
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