Abstract
The Bi atom in the title compound, (CH6N3)(2)[Bi-(C18H25N4O12)].4H(2)O, is nine-coordinated through four N and five O atoms of the ttha ligand, where ttha denotes triethylenetetraminehexaacetate. The noncoordinated COOH group is involved in a strong hydrogen bond with an O atom of a neighbouring complex, thereby forming dimeric units.
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