Abstract
Reaction of gallium(III) nitrate with (E)-1-[1-(2-pyridyl)ethylidene]thiosemicarbazide (petc) afforded the title complex, [Ga(C8H9N4S)2]NO3. The title complex contains one GaIII cation and two enol-form petc anions, accompanied by one charge-balancing disordered nitrate anion. The petc is in the enol form, coordinating to the GaIII centre via one S atom and two N atoms. Thus, the GaIII centre assumes a distorted octahedral coordination geometry.
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