Abstract
Reaction of nickel(II) chloride with sodium dicyanamide and pyridazine leads to single crystals of the title compound, [Ni{N(CN)2}2(C4H4N2)4], in which the NiII cation is octahedrally coordinated by two dicyanamide anions and four pyridazine ligands into a discrete complex that is located on a center of inversion.
Highlights
Reaction of nickel(II) chloride with sodium dicyanamide and pyridazine leads to single crystals of the title compound, [Ni{N(CN)2}2(C4H4N2)4], in which the NiII cation is octahedrally coordinated by two dicyanamide anions and four pyridazine ligands into a discrete complex that is located on a center of inversion
C4—H4 N11—C14 N11—N12 N12—C11 C11—C12 C11—H11 C12—C13 C12—H12 C13—C14 C13—H13 C14—H14 N21—C21
Summary
Key indicators: single-crystal X-ray study; T = 170 K; mean (C–C) = 0.006 A; R factor = 0.048; wR factor = 0.097; data-to-parameter ratio = 13.3. Crystal data [Ni(C2N3)2(C4H4N2)4] Mr = 511.18 Triclinic, P1 a = 8.1796 (12) Ab = 8.4125 (12) Ac = 8.9643 (11) A = 81.364 (16) = 66.027 (15)
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