Abstract
In the title complex, [Zn(NCO)2(C7H8N4)2], the ZnII ion exhibits a distorted tetrahedral coordination geometry. The coordination environment is formed by two 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine (dmtp) ligands, coordinated through the N atom in position 3, and two cyanate anions interacting by their N atoms. Supramolecular dimers are generated by stacking interactions between the pyrimidine rings of two ligands related by an inversion center [centroid–centroid distance = 3.5444 (18) Å].
Highlights
In the title complex, [Zn(NCO)2(C7H8N4)2], the ZnII ion exhibits a distorted tetrahedral coordination geometry
The coordination environment is formed by two 5,7-dimethyl1,2,4-triazolo[1,5-a]pyrimidine ligands, coordinated through the N atom in position 3, and two cyanate anions interacting by their N atoms
Supramolecular dimers are generated by stacking interactions between the pyrimidine rings of two ligands related by an inversion center [centroid
Summary
R factor = 0.039; wR factor = 0.106; data-to-parameter ratio = 16.6. In the title complex, [Zn(NCO)2(C7H8N4)2], the ZnII ion exhibits a distorted tetrahedral coordination geometry. The coordination environment is formed by two 5,7-dimethyl1,2,4-triazolo[1,5-a]pyrimidine (dmtp) ligands, coordinated through the N atom in position 3, and two cyanate anions interacting by their N atoms. Supramolecular dimers are generated by stacking interactions between the pyrimidine rings of two ligands related by an inversion center [centroid– centroid distance = 3.5444 (18) Å].
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
