Abstract
The title compound, [BaCl2(C2H6SO)], forms a Ba6Cl9 cluster in which the BaCl2 units are connected via dimethylsulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba6Cl9 cluster is located on a threefold inversion axis and is coordinated octahedrally to six barium cations. In the crystal, the clusters are arranged in rows, which are interconnected by the DMSO molecules, forming a three-dimensional network.
Highlights
The title compound, [BaCl2(C2H6SO)], forms a Ba6Cl9 cluster in which the BaCl2 units are connected via dimethylsulfoxide (DMSO) and chloride bridges
Ba6Cl9 cluster is located on a threefold inversion axis and is coordinated octahedrally to six barium cations
The clusters are arranged in rows, which are interconnected by the DMSO molecules, forming a three-dimensional network
Summary
Max Planck Institute for Solid State Research, Heisenbergstrasse 1, 70569 Stuttgart, Germany. R factor = 0.023; wR factor = 0.057; data-to-parameter ratio = 32.9. The title compound, [BaCl2(C2H6SO)], forms a Ba6Cl9 cluster in which the BaCl2 units are connected via dimethylsulfoxide (DMSO) and chloride bridges. Ba6Cl9 cluster is located on a threefold inversion axis and is coordinated octahedrally to six barium cations. The clusters are arranged in rows, which are interconnected by the DMSO molecules, forming a three-dimensional network. Data collection: X-AREA (Stoe & Cie, 2009); cell refinement: XAREA; data reduction: X-RED32 (Stoe & Cie, 2009); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 2006); software used to prepare material for publication: publCIF (Westrip, 2010)
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