Abstract
In the title compound, [Ni(C17H14N3S2)2]·2C3H7NO, the Ni atom (site symmetry ) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In the crystal structure, an N—H⋯O hydrogen bond links the complex to the dimethylformamide solvent molecule.
Highlights
In the title compound, [Ni(C17H14N3S2)2]Á2C3H7NO, the Ni atom is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry
An N—HÁ Á ÁO hydrogen bond links the complex to the dimethylformamide solvent molecule
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HB2849)
Summary
In the title compound, [Ni(C17H14N3S2)2]Á2C3H7NO, the Ni atom (site symmetry 1) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. Received 15 November 2008; accepted 19 November 2008 Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.004 A; R factor = 0.040; wR factor = 0.094; data-to-parameter ratio = 13.8.
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