Abstract
In the title complex, [Mn(N3)2(C8H8N6)2], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octahedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two azide anions. The two chelated 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands form a dihedral angle 74.75 (5)°. The mononuclear molecules are alternatively linked into layers parallel to the ac plane via N—H⋯N hydrogen bonds. Adjacent layers are connected into a three-dimensional supramolecular framework by futher N—H⋯N hydrogen-bonding interactions.
Highlights
In the title complex, [Mn(N3)2(C8H8N6)2], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octahedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine2,4-diamine ligands and two N atoms from two azide anions
The mononuclear molecules are alternatively linked into layers parallel to the ac plane via N—H N hydrogen bonds
Adjacent layers are connected into a three-dimensional supramolecular framework by futher N—H N hydrogen-bonding interactions
Summary
In the title complex, [Mn(N3)2(C8H8N6)2], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octahedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine2,4-diamine ligands and two N atoms from two azide anions. The two chelated 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands form a dihedral angle 74.75 (5). The mononuclear molecules are alternatively linked into layers parallel to the ac plane via N—H N hydrogen bonds. Adjacent layers are connected into a three-dimensional supramolecular framework by futher N—H N hydrogen-bonding interactions. Data collection: APEX2 (Bruker, 2004); cell refinement: SAINT (Bruker, 2004); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL
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