Abstract
In the title complex, [Zn(N3)2(C7H10N2)2], the ZnII atom is coordinated by two N atoms from two 4-(dimethylamino)pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetrahedral coordination geometry. In the crystal, weak C—H⋯N hydrogen bonds between the DMAP and azide ligands link these discrete complex molecules into a three-dimensional supramolecular network.
Highlights
Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université
In the title complex, [Zn(N3)2(C7H10N2)2], the ZnII atom is coordinated by two N atoms from two 4-(dimethylamino)pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetrahedral coordination geometry
The title complex (I), is a mononuclear Zn(II) complex, consisting of two 4-dimethylaminopyridine (DMAP) ligands and two azide anions (Figure 1), all ligands coordinating in a monodentate manner
Summary
Weak C—H N hydrogen bonds between the DMAP and azide ligands link these discrete complex molecules into a three-dimensional supramolecular network
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