Bis(η5-cyclopentadienyl)[μ-(4b,5,5a-η3:9b,10,10a-η3)-2,3,7,8-tetrakis(trimethylsilyl)benzo[3,4]cyclobuta[1,2-b]biphenylene]-syn-dicobalt (Co–Co), a Dinuclear π-Complex of the Linear [3]Phenylene Framework

K Peter C Vollhardt,Jonathan J Wong,Robin Padilla,Kendall N Houk

doi:10.1055/a-1659-7656

Bis(η5-cyclopentadienyl)[μ-(4b,5,5a-η3:9b,10,10a-η3)-2,3,7,8-tetrakis(trimethylsilyl)benzo[3,4]cyclobuta[1,2-b]biphenylene]-syn-dicobalt (Co–Co), a Dinuclear π-Complex of the Linear [3]Phenylene Framework

K Peter C Vollhardt, Jonathan J Wong + Show 2 more

https://doi.org/10.1055/a-1659-7656

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Journal: Synlett

Publication Date: Oct 14, 2021

Affiliation: University of California, Berkeley

#Relative Stability #Title Compound + Show 1 more

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Abstract

AbstractThe title compound was made by the reaction of the CpCo-complex of 2,3,7,8-tetrakis(trimethylsilyl) linear [3]phenylene, in which the metal coordinates one of the cyclobutadiene rings, with CpCo(C2H4)2. Because of its relative stability, a syn-dicobalt-bound configuration is indicated rather than its anti alternative.

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