Abstract
The TiIV atom in the title compound, [Ti(C9H5ClNO)2(C3H7O)2], is chelated by the substituted quinolin-8-olate anions in a distorted octahedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other. One C atom of one propan-2-olate group is disordered over two positions with occupancies of 0.733 (8):0.267 (8).
Highlights
The TiIV atom in the title compound, [Ti(C9H5ClNO)2(C3H7O)2], is chelated by the substituted quinolin-8-olate anions in a distorted octahedral geometry
The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other
One C atom of one propan-2-olate group is disordered over two positions with occupancies of 0.733 (8):0.267 (8)
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.004 A; disorder in main residue; R factor = 0.039; wR factor = 0.102; data-to-parameter ratio = 17.2. Crystal data [Ti(C9H5ClNO)2(C3H7O)2] Mr = 523.25 Triclinic, P1 a = 8.2170 (2) Ab = 12.1847 (3) Ac = 13.8113 (3) A = 109.555 (1) = 105.090 (1)
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