Abstract
The title compound, [Zn(C7H4FO2)2(C6H6N2O)2]·H2O, is a monomeric complex. It contains two 4-fluorobenzoate and two nicotinamide ligands and one uncoordinated water molecule. The 4-fluorobenzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The six-coordinate geometry around the ZnII atom may be described as highly distorted octahedral, with the two nicotinamide ligands arranged cis. Intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a supramolecular structure.
Highlights
Structure Reports OnlineKey indicators: single-crystal X-ray study; T = 294 K; mean (C–C) = 0.005 A; R factor = 0.058; wR factor = 0.153; data-to-parameter ratio = 14.7
The title compound, [Zn(C7H4FO2)2(C6H6N2O)2]ÁH2O, is a monomeric complex
Intermolecular O—HÁ Á ÁO and N— HÁ Á ÁO hydrogen bonds link the molecules into a supramolecular structure
Summary
Key indicators: single-crystal X-ray study; T = 294 K; mean (C–C) = 0.005 A; R factor = 0.058; wR factor = 0.153; data-to-parameter ratio = 14.7. The title compound, [Zn(C7H4FO2)2(C6H6N2O)2]ÁH2O, is a monomeric complex. It contains two 4-fluorobenzoate and two nicotinamide ligands and one uncoordinated water molecule. The 4-fluorobenzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The sixcoordinate geometry around the ZnII atom may be described as highly distorted octahedral, with the two nicotinamide ligands arranged cis. Intermolecular O—HÁ Á ÁO and N— HÁ Á ÁO hydrogen bonds link the molecules into a supramolecular structure
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